AppHarbor. I can't wait till I've got some spare time to go play with what they're doing. I suspect they're going to be ridiculously big even if .NET isn't very popular in these parts.
Grubwith.us is really appealing to me. I've wished for something like that for some time now. If I could make it, I'd be grubbing with them today..<p>I also think the concept is very appealing to restaurants as well. Adding value for everyone seems like a sure win to me.