Referencing atomic orbitals... for a good time, ask ChatGPT this series of questions:<p>1. Hello, what can you tell me about the Legendre polynomials, angular momentum, and the three-dimensional visualization of atomic orbitals in the context of quantum mechanics?<p>2. So, can the three-dimensional representations of atomic orbitals seen in chemistry textbooks be considered to be solutions of the Schrodinger differential equations in the context of Legendre polynomials?<p>3. What's the nature - mathematically speaking - of the radial and angular combination of the Legendre polynomials and the hydrogenic radial functions that give rise to the textbook probablility density visualizations of atomic orbitals?<p>4. Tell me about Hartree-Fock representations of the molecular orbitals of the helium atom?<p>5. Compare and contrast the Hartree-Fock method and the more recently developed Density Functional Theory approach, please, in the context of simple molecular orbital theory.<p>That's pretty impressive, probably a better and more concise explanation than a lot of professionals in the field could give off the top of their heads. However, it's also interesting to see where ChatGPT is remarkable untrustworthy - Linux terminal command line options, for example, it often gets those wrong (disastrously so in some cases, happily I double-checked first). It also has problems with modular arithmetic... This one always delivers, it seems, and has been doing so for a month at least:<p>Q: So is seven congruent to four, in the context of modulus three?<p>> "No, seven is not congruent to four modulo three. To determine whether two integers are congruent modulo a given modulus, we need to compute the difference between them and check if it is divisible by the modulus.<p>In this case, we have:<p>7 - 4 = 3<p>Since 3 is not divisible by 3, we conclude that 7 is not congruent to 4 modulo 3.<p>We can also verify this by checking the remainders when 7 and 4 are divided by 3:<p>7 ÷ 3 = 2, remainder 1
4 ÷ 3 = 1, remainder 1<p>Since the remainders are not the same, we can again conclude that 7 is not congruent to 4 modulo 3."<p>Hmmm.... this seems wrong...