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Charging lithium-ion batteries at high currents first increases lifespan by 50%

249 点作者 snazz8 个月前

13 条评论

starky8 个月前
From having worked a bit in the industry I&#x27;m a bit skeptical about this study, I&#x27;ve definitely seen studies and experiments that used different initial charging conditions that would have shown better fade performance if this was true.<p>Not to mention, how much does the increased SEI change the impedance of the cell (thus reducing the subsequent charge speed) and the capacity available.
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mensetmanusman8 个月前
Such a cool finding if it pans out in production. A hidden process variable hiding in plain sight.
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rkagerer8 个月前
TLDR: During a battery&#x27;s initial &quot;formation&quot; charge, some of the lithium deactivates, forming a squishy, protective layer around the negative electrode, called the solid electrolyte interphase (SEI). Today, manufacturers typically do a slow formation charge, during which about 9% of the lithium is lost to the SEI. It was thought this was needed to form a robust layer. But the researchers found at the higher initial charge currents used in this study, 30% becomes SEI - so you loose some battery capacity (for a given amount of lithium), but wind up with a beefier protective layer on your electrode and better longevity across subsequent charge cycles.
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sharpshadow8 个月前
I was able to revive lithium batteries which have been discharged to much and didn’t charge by connecting them to a fully charged one for a couple of seconds.
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mleonhard8 个月前
Since a good SEI layer on the electrode is important, couldn&#x27;t they put the layer on the electrode before assembling the battery? Then they could make the layer&#x27;s shape more even.
dzhiurgis8 个月前
Whats a battery lifespan? Is it capacity degradation or random failure?<p>If discovery slows down capacity degradation, but now your EV battery is 100x more likely spontaneously fail ($$$) - it&#x27;s not really an improvement. Maybe ok for consumer device tho.
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jostmey8 个月前
I’m confused… Is this just a prediction or has it been experimentally verified?
Euphorbium8 个月前
I remember a recent paper that found that charging at double the current, but at 2khz frequency square wave basically eliminated battery degradation.
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keepamovin8 个月前
Probably burns in the microstructure making it more stable to filament formation, like the way high voltage electricity etches wood.
fencepost8 个月前
TL;DR the high current causes a layer on the negative electron to form a bit differently (and obviously faster), previously it was thought that a slower initial charge led to better formation. This is a process tweak incremental improvement, not anything truly fundamental.
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westurner8 个月前
But are there risks and thus costs?
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solarkraft8 个月前
Rule of thumb: It’s a battery innovation&#x2F;“breakthrough”, so the chance it’ll reach the market any time soon is slim.
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userbinator8 个月前
<i>is 30 times faster</i><p>Faster than <i>what?</i><p>It turns out this is about the very first charge after assembly of the cell, not regular use.<p>However, I doubt that this finding will be used much, except perhaps in applications like aerospace; it is in manufacturer&#x27;s economic interests that their products have short lives.<p>Edit: looks like as usual, comments that expose the truth get buried ;-)
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